| Laser Induced Flourescence (UVOST)Gregg Drilling conducts Laser Induced Fluorescence (LIF) Cone Penetration Tests using a UVOST module that is located behind the standard piezocone, Figure UVOST. The laser induced fluorescence cone works on the principle that polycyclic aromatic hydrocarbons (PAH’s), mixed with soil and/or groundwater, fluoresce when irradiated by ultra violet light. Therefore, by measuring the intensity of fluorescence, the lateral and vertical extent of hydrocarbon contamination in the ground can be determined.
The UVOST module uses principles of fluorescence spectrometry by irradiating the soil with ultra violet light produced by a laser and transmitted to the cone through fiber optic cables. The light is then passes through a small window in the side of the cone into the soil. Any hydrocarbon molecules present in the soil absorb the light energy during radiation and immediately re-emit the light at a longer wavelength. This re-emission is termed fluorescence. The UVOST system also measures the emission decay with time at four different wavelengths (350nm, 400nm, 450nm, and 500nm). This allows the software to determine a product “signature” at each data point. This process allows determination of the type of contaminant as shown in Figure Concept.
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| Figure UVOST: UVOST system deployed with the CPT | In general, the typical detection limit for the UVOST system is <100 ppm and it will operate effectively above and below the saturated zone. With the capability to push up to 600 feet per day, laser induced fluorescence offers a fast and efficient means for delineating PAH contaminant plumes. Color coded logs offer qualitative information in a quick glance and can be produced in the field for real-time decision making. Coupled with the data provided by the CPT, a complete site assessment can be completed with no samples or cuttings, saving laboratory costs as well as site and environmental impact. | 
| Figure Concept (figure courtesy of Dakota Technologies) | Hydrocarbons detected with UVOST | Hydrocarbons rarely detected using UVOST | Gasoline | Extremely weathered gasoline | Diesel | Coal tar | Jet (Kerosene) | Creosote | Motor Oil | Bunker Oil | Cutting fluids | Polychlorinated bi-phenols (PCB’s) | Hydraulic fluids | Chlorinated solvent DNAPL | Crude Oil | Dissolved phase (aqueous) PAH’s |
Potential False Positives (fluorescence observed) | Potential False Negatives (do not fluoresce) | Sea-shells (weak-medium) | Extremely weathered fuels (especially gasoline) | Paper (medium-strong depending on color) | Aviation gasoline (weak) | Peat/meadow mat (weak) | Coal tars (most) | Calcite/calcareous sands (weak) | Creosotes (most) | Tree roots (weak-medium) | “Dry” PAHs such as aqueous phase, lamp black, purifier chips | Sewer lines (medium-strong) | Most chlorinated solvents | | Benzene, toluene, zylenes (relatively pure) |
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| | Printable Version of UVOST Log Reference |
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